An identity store is the system of record for the organisation's identities — employees, contractors, service accounts, partners, customers, machines. It is a product. There are many competent ones.
An identity architecture is the design of how those identities are used. It names the trust boundaries, the authorisation model, the lifecycle, and the verification model — how a system can prove a decision was made correctly and on the right evidence.
In practice the store is a few months' work and the architecture is several years. The store is what you buy. The architecture is what you build.